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The Chemistry of Cookery

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The Chemistry of Cookery

by Williams, W. Mattieu (William Mattieu) · Page 180 of 286 · 99,981 words

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that the vegetable casein is not of the same composition as animal casein, are correct. The following figures display my justification for thus lightly treating the discussion: +--------------------+--------+---------+---------+---------+ | -- | Casein | Legumin | Legumin | Legumin | +--------------------+--------+---------+---------+---------+ | Carbon | 53·7 | 50·50 | 55·05 | 56·24 | | Hydrogen | 7·2 | 6·78 | 7·59 | 7·97 | | Nitrogen | 16·6 | 18·17 | 15·89 | 15·83 | | Oxygen and Sulphur | 22·5 | 24·55 | 21·47 | 19·96 | +--------------------+--------+---------+---------+---------+ The first column shows the results of Dumas for animal casein; the second, those of Dumas and Cahours for legumin; the third, those of Jones for the same; and the fourth, those of Rochleder; all as quoted by Lehmann. Here it will be seen that the differences upon which Dumas and Cahours base their supposed refutation of the identity of the animal with the vegetable principle are much smaller than the differences between the results of different analyses of the latter. These differences I suspect are all due to the difficulty of isolating the substances in question, especially of the vegetable substance, which is so intimately mixed with the starch, &c., in its natural condition that complete separation is of questionable possibility. The difficulty (or impossibility) of driving off all the adhering water, without removing the combined elements of water, is a further source of discrepancy. This will be understood by the following description of the method of separation as given by Miller (‘Elements of Chemistry,’ vol. iii.). ‘Legumin is usually extracted from peas or from almonds, by digesting the pulp of the crushed seeds in warm water for two or three hours. The undissolved portion is strained off by means of linen, and the turbid liquid allowed to deposit the starch which it holds in suspension; it is then filtered and mixed with dilute acetic acid. A white flocculent precipitate is thus formed, which must be collected on a filter and washed.’ This is but a mechanical process, and its liability to variation in result may be learned by anybody who will

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