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The Chemistry of Cookery

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The Chemistry of Cookery

by Williams, W. Mattieu (William Mattieu) · Page 177 of 286 · 99,981 words

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to its original _apparently_ smaller degree of porosity. That this change can be only apparent is evident from the facts that the total quantity of solid material in the loaf remains the same, and its total dimensions are retained more or less completely by the rigidity of the crust. I say ‘more or less,’ because this depends upon the thickness and hardness of the crust, and also upon the completeness of its surrounding. Lightly-baked loaves shrink a little in dimensions in becoming stale, and partly regain the loss on reheating, but this difference only exaggerates the apparent paradox of varying porosity, as the diminished bulk of a given quantity of material displays increased porosity, and the increase of total dimensions accompanies the diminished porosity. I have obtained a reconciliation of this paradox by careful examination of the structure of the crumb. This shows that the larger or decidedly visible pores are cells having walls of somewhat silky appearance. The silky lustre and structure is, I have no doubt, due to a varnish of dextrin, the gummy nature of which I have already described. On looking a little more closely at this inner surface of the big blow-holes with the aid of a hand-lens of moderate power, I find that it is not a continuous varnish of gum, but a net-work or agglomeration of gummy fibres and particles, barely touching each other. My theory of the change that takes place as the bread becomes stale is, that these fibres and particles gradually approach each other either by shrinkage or adhesive attraction, and thus consolidate and harden the walls of each of the millions of easily visible pores, these walls forming the solid material of which the loaf is made up. In doing so they naturally increase the dimensions of the visible pores, while the microscopic interstices or spaces between the minute fibres of the cell walls are diminished by the approximation or adhesion of the fibres to each other. This adhesion is probably aided by an oozing out or efflorescence of the vapour held by the fibres, and its condensation on

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