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The Chemistry of Cookery
by Williams, W. Mattieu (William Mattieu) · Page 154 of 286 · 99,981 words
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the swollen granules still remain as separate bodies and slowly sink, though a considerable exosmosis of the true starch has occurred, as shown by the thickening of the water. I suppose that in their original state the enveloping membrane is much folded, and that these folds form the curious marking of concentric rings which constitutes the characteristic microscopic structure of starch granules, and that when cooked, at the temperature named, the very delicate membrane becomes fully distended by the increased bulk of the hydrated and diluted starch, and thus the rings disappear. A very little mechanical violence, mere stirring, now breaks up these distended granules, and we obtain the starch paste so well known to the laundress, and to all who have seen cooked arrowroot. If this paste be dried by evaporation it does not regain its former insolubility, but readily dissolves in hot or cold water. This is what I should describe as cooked starch. If the heat is now raised from 140° to the boiling point, and the boiling continued, the gelatinous mass becomes thicker and thicker; and if there are more than fifty parts of water to one of starch a separation takes place, the starch settling down with its fifty parts of water, the excess of water standing above it. Carefully dried starch may be heated to above 300° without becoming soluble, but at 400° a remarkable change commences. The same occurs to ordinary commercial starch at 320°, the difference evidently depending on the water retained by it. If the heat is continued a little beyond this it is converted into _dextrin_, otherwise named ‘British gum,’ ‘gommeline,’ ‘starch gum,’ and ‘Alsace gum,’ from its resemblance to gum-arabic, for which it is now very extensively substituted. Solutions of this in bottles are sold in the stationers’ shops under various names for desk uses. The remarkable feature of this conversion of starch into dextrin is, that it is accompanied by no change of chemical composition. Starch is composed of six equivalents of carbon, ten of hydrogen, and five of oxygen—C_{6}H_{10}O_{5}, _i.e._ six of carbon and five of water
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